Journal of Physical Chemistry
Paper

Comparison of Monte Carlo and HNC/MSA excess charge adsorption isotherms for an electrical double layer containing divalent ions

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Abstract

An excess charge adsorption isotherm for a 2 electrolyte is calculated from the recent Monte Carlo data of Torrie and Valleau. The errors in the Gouy-Chapman isotherms are even larger than indicated by the HNC/MSA calculations. © 1983 American Chemical Society.

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