Molecular structure of dimethyl(2,4-pentanedionato)gold(III)

Shuzo Shibata; Kinya Iijima; Thomas H. Baum

doi:10.1039/DT9900001519

Journal of the Chemical Society, Dalton Transactions

Paper

01 Dec 1990

Molecular structure of dimethyl(2,4-pentanedionato)gold(III)

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Abstract

A gas-phase electron diffraction study of dimethyl(2,4-pentanedionato)gold(III) indicates a square-planar structure with ra(Au-O) = 2.085(7), ra(Au-C) = 2.054(5) Å, angle OAuO 90.9(6)°, and CAuC 92.7(24)°, as well as the normal parameters of an acetylacetone ligand.

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Abstract

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Synthesis and Characterization of a Bis(μ-β-diketonato)bis((1,2,5,6-η)-1,5-dimethyl-1,5-cyclooctadiene) disilver Complex. An Intermediate in the Synthesis of an Isomerically Pure (β-Diketonato)((1,2,5,6-η)-1,5-dimethyl-1,5-cyclooctadiene)copper(I) Complex

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Alkyne complexes of copper(I) (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato): Syntheses and characterization of (η2-bis(trimethylsilyl)acetylene) copper(I) (hfac), (μ-η1-bis(trimethylsilyl)acetylene) bis(copper(I) (hfac)) and a series of (η2-alkyne) Cu(hfac) complexes

Alkyne complexes of copper(I) (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato): Syntheses and characterization of (η²-bis(trimethylsilyl)acetylene) copper(I) (hfac), (μ-η¹-bis(trimethylsilyl)acetylene) bis(copper(I) (hfac)) and a series of (η²-alkyne) Cu(hfac) complexes