Heinz Schmid, Hans Biebuyck, et al.
Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures
Paper
Vibrational and electronic properties of cyanide adsorbed on metal electrodes
Abstract
The origin of the potential dependence of the high vibration frequency vCN is explained as a Stark effect. It is shown by means of ab initio cluster calculations that the coupling of vCN to the low frequency metal-ligand stretch plays a crucial role. © 1987.
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